Date of Award
Union College Only
Bachelor of Science
In order to analyze the magnitude and factors which effect 13C-13C NMR coupling through a metal center, we have synthesized an octahedral dicyano cobalt (III) complex in which two trans cyanides are chemically non-equivalent. Although similar complexes have been reported, their spectroscopic characterization with isotopically labeled cyanide (13CN) has yet to be studied in detail.
Wayman, Derek D., "The synthesis and characterization of a metal complex containing chemically non-equivalent axial cyanide ligands" (2006). Honors Theses. 2106.